Supporting Information Exploring Matrix Effects on Photochemistry of Organic Aerosols
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Exploring matrix effects on photochemistry of organic aerosols.
This work explores the effect of the environment on the rate of photolysis of 2,4-dinitrophenol (24-DNP), an important environmental toxin. In stark contrast to the slow photolysis of 24-DNP in an aqueous solution, the photolysis rate is increased by more than an order of magnitude for 24-DNP dissolved in 1-octanol or embedded in secondary organic material (SOM) produced by ozonolysis of α-pine...
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In the present study, the impact of aerosols on the photochemistry in Mexico City is evaluated using the WRFCHEM model for the period from 24 to 29 March during the MCMA-2006/MILAGRO campaign. An aerosol radiative module has been developed with detailed consideration of aerosol size, composition, and mixing. The module has been coupled into the WRF-CHEM model to calculate the aerosol optical pr...
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Atmospheric Chemistry and Physics Discussions This discussion paper is/has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP if available. Abstract In the present study, the impact of aerosols on the photochemistry in Mexico City is evaluated using the WRF-CHEM model for the period from 24 to 29 March during the MCMA-...
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The unimolecular photochemistry of aldehydes has been extensively studied, both experimentally and computationally. However, less is known about the role of cross-molecular photochemical processes in the condensed-phase photolysis of aldehydes. The triplet-state photochemistry of pentanal in its pentameric (n = 5) cluster was investigated as a model for photochemical reactions of aliphatic alde...
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Due to the effect of aerosols present in the atmosphere on the satellite images, the study of the effect of local aerosols distribution on the satellite images is important. On the other hand, the study shows that the effect of aerosols on the greenhouse gases and consequently on climate is also undeniable and as a result, this puts more emphasize on the necessity of this study. Lack of informa...
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تاریخ انتشار 2014